Bis(2-amino-6-methyl-1,3-benzothiazole-κN 3)bis(4-nitrobenzoato-κO 1)zinc
نویسندگان
چکیده
In the title mononuclear complex, [Zn(C(7)H(4)NO(4))(2)(C(8)H(8)N(2)S)(2)], the Zn(II) atom is coordinated by two N atoms from two 2-amino-6-methyl-1,3-benzothia-zole and by two carboxylate O atoms from two 4-nitro-benzoate ligands, adopting a slightly distorted tetra-hedral coordination geometry. In the crystal, inter-molecular N-H⋯O hydrogen bonds between the amino group of 2-amino-6-methyl-1,3-benzothia-zole and the carboxyl-ate group of 4-nitro-benzoate link these discrete mononuclear units into a one-dimensional supra-molecular chain extending parallel to [100].
منابع مشابه
Bis(3-hydroxypyridine-κN)bis(3-nitrobenzoato-κO)zinc(II)
The title complex, [Zn(C(7)H(4)NO(4))(2)(C(5)H(5)NO)(2)], has site symmetry 2. The Zn(II) ion is located on a crystallographic twofold rotation axis and assumes a distorted tetra-hedral ZnN(2)O(2) coordination geometry. Mol-ecules are linked by an inter-molecular O-H⋯O hydrogen bond and π-π stacking inter-actions between pyridine rings [centroid-centroid speparation 3.594 (1) Å].
متن کاملBis[4-(methylamino)benzoato-κO]bis(nicotinamide-κN)zinc(II)
The title zinc complex, [Zn(C(8)H(8)NO(2))(2)(C(6)H(6)N(2)O)(2)], is composed of two monodentate 4-(methyl-amino)benzoate and two monodentate nicotinamide ligands. The coordination around the Zn atom is distorted tetra-hedral. The dihedral angles between the two benzene rings and the two pyridine rings are 78.30 (6) and 68.86 (5)°. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds ...
متن کاملBis[(1S,1′S)-1,1′-(4-amino-4H-1,2,4-triazole-3,5-diyl)diethanol-κN 1]bis(nitrato-κO)zinc
In the title homochiral mononuclear compound, [Zn(NO(3))(2)(C(6)H(12)N(4)O(2))(2)], the Zn(II) atom is located on a twofold rotation axis and coordinated by two N atoms from two ligands and two O atoms from two NO(3) (-) anions, adopting a distorted tetra-hedral coordination geometry. The compound is enanti-omerically pure and corresponds to the S diastereoisomer, with the optical activity orig...
متن کامل(μ-Acetato-κ2 O:O′)[μ-2,6-bis({bis[(pyridin-2-yl-κN)methyl]amino-κN}methyl)-4-methylphenolato-κ2 O:O](methanol-κO)dizinc bis(perchlorate)
The binuclear title complex, [Zn2(C33H33N6O)(CH3COO2)(CH3OH)](ClO4)2, was synthesized by the reaction between 2,6-bis-({[bis-(pyridin-2-yl)meth-yl]amino}-meth-yl)-4-methyl-phenol (H-BPMP), Zn(OAc)2 and NaClO4. The two Zn(II) ions are bridged by the phenolate O atom of the octadentate ligand and the acetate group. An additional methanol ligand is terminally coordinated to one of the Zn(II) ions,...
متن کامل[μ-1,3-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN 2)propan-2-olato-κ2 O:O]bis[(ethanol-κO)zinc(II)] bis(perchlorate)
In the centrosymmetric dinuclear title complex, [Zn(2)(C(13)H(19)N(4)O)(2)(C(2)H(5)OH)(2)](ClO(4))(2), the Zn(II) atom is in a distorted trigonal-bipyramidal coordination geometry. The equatorial plane is constructed by one N atom and one O atom from two 1,3-bis-(3,5-dimethyl-pyrazol-1-yl)propan-2-olate (bppo) ligands and one O atom from an ethanol mol-ecule. One N atom and one O atom from the ...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011